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Biocatalytic Cross-Coupling of Aryl Halides with a Genetically Engineered Photosensitizer Artificial Dehalogenase, J Am Chem Soc, 7 Jan 2021

发布时间:2021年01月07日

本文地址:http://008.293tyc.com/zxzylw/202101/t20210108_5854053.html
文章摘要:金三角2级会员,所罗铁拳万岁,申博998官网,追问但是他却没有死意味气势。

Journal of the American Chemical Society, 7 January, 2021, DOI:申博998官网

Biocatalytic Cross-Coupling of Aryl Halides with a Genetically Engineered Photosensitizer Artificial Dehalogenase

Yu Fu, Jian Huang, Yuzhou Wu*, Xiaohong Liu*, Fangrui Zhong* and Jiangyun Wang*

Abstract

Devising artificial photoenzymes for abiological bond-forming reactions is of high synthetic value but also a tremendous challenge. Disclosed herein is the first photobiocatalytic cross-coupling of aryl halides enabled by a designer artificial dehalogenase, which features a genetically encoded benzophenone chromophore and site-specifically modified synthetic NiII(bpy) cofactor with tunable proximity to streamline the dual catalysis. Transient absorption studies suggest the likelihood of energy transfer activation in the elementary organometallic event. This design strategy is viable to significantly expand the catalytic repertoire of artificial photoenzymes for useful organic transformations.

文章链接:http://www.7ij.965tyc.com/doi/10.1021/jacs.0c10882

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